Scaling of activation energy for macroscopic flow in poly(ethylene glycol) solutions: Entangled – Non-entangled crossover

We postulate an empirical scaling equation, which accurately describes flow of polymer solutions, complimenting the paradigm of length-scale-dependent viscosity. We investigated poly(ethylene glycol) aqueous solutions and observed an exponential dependence of viscosity on the hydrodynamic radius of a single coil R_h divided by the correlation length ξ. Properties of the system changed abruptly with the onset of chain entanglement at concentration corresponding to ξ = R_h. We propose a single equation valid for all the investigated systems, analyze the physical meaning of parameters appearing therein and discuss the impact of chain entanglement. Viscous flow is treated as an activated process, following the Eyring rate theory. We show that the difference of activation energy for flow between pure solvent and polymer solution, ΔE_a, is a function of concentration, whose derivative has a discontinuity at the crossover concentration. For dilute PEG solutions ΔE_a takes values of up to several kJ/mol and is proportional to the intrinsic viscosity. We successfully apply the scaling approach to the diffusive motion of a protein (aldolase) in solutions of 25 kg/mol PEO (concentrations of 2–20%), investigated by fluorescence correlation spectroscopy (FCS). A significant difference in the influence of crowding on translational and rotational motion of the protein is revealed.     

Optimal design of a Kirchhoff-Love plate of variable thickness by application of the minimum principle

Structural and Multidisciplinary Optimization - An approximate thickness optimization of a rectangular Kirchhoff-Love plate with variable stiffness under uniform load is performed in this paper....     

Multi-device anonymous authentication

Recently, a few pragmatic and privacy protecting systems for authentication in multiple systems have been designed. The most prominent examples include Pseudonymous Signatures for German personal identity cards and Anonymous Attestation. The main properties are that a user can authenticate himself with a single private key (stored on a smart card), but nevertheless the user’s IDs in different systems are unlinkable. We develop a solution which enables a user to achieve the above-mentioned goals while using more than one personal device, each holding a single secret key, but different for each device. Our solution is privacy preserving: it will remain hidden for the service system which device is used. Nevertheless, if a device gets stolen, lost or compromised, the user can revoke it (leaving his other devices intact). In particular, in this way we create a strong authentication framework for cloud users, where the cloud does not learn indirectly personal data. Our solution is based on a novel cryptographic primitive, called Pseudonymous Public Key Group Signature.

     

Dielectric properties of vanadium doped barium titanate synthesized via high-energy ball milling

The study shows the advisability of using a mechanochemical synthesis method, based on a high-energy planetary ball milling, to a modification of barium titanate by a vanadium doping. This method improves useful properties of BaTi_0:95V_0:05O₃ as a capacitor material. It has a high value of electric permittivity ?′ in the wide range of temperature and low dielectric losses ?″ as well as a low electrical conductivity.     

Influence of platelet-activating factor,lyso-platelet-activating factor and edelfosine on Langmuir monolayers imitating plasma membranes of cell lines differing in susceptibility to anti-cancer treatment: the effect of plasmalogen level

Three structurally related but differing in biological activities single-chained ether phospholipids (PAF (platelet-activating factor) and lyso-PAF) and an anti-cancer drug (edelfosine (ED)) were investigated in Langmuir monolayers imitating natural membranes. The aim of the undertaken experiments was to study the influence of these lipids on monolayers mimicking plasma membranes of cell lines differing in susceptibility to the anti-cancer activity of ED, i.e. promyelocytic leukaemia cells (HL-60) and promyeloblastic leukaemia cells (K-562). As these cells differ essentially in the cholesterol/phospholipid ratio and plasmalogen concentration in the membrane, we have carried out systematic investigations in artificial systems of various compositions. The results for model leukaemia cell membrane were compared with data acquired for systems imitating normal leucocytes. Our results show that the level of plasmalogens significantly modulates the influence of the single-chained phospholipids on the investigated systems. The experiments confirmed also that the interactions of ether lipids with a model membrane of HL-60 cells (in biological tests sensitive to ED) have opposite character when compared with K-562, being resistant to ED. Moreover, the values of the parameters characterizing monolayers serving as membrane models (strength of interactions, monolayers fluidity and morphology) proved both sensitivity of these cells to ED and lack of their susceptibility towards PAF. Interestingly, it has been found that lyso-PAF, which is usually described as an inactive precursor of PAF, displays a stronger effect on HL-60 model membranes than ED.     

Combined use of cocoa dietary fibre and steviol glycosides in low‐calorie muffins production

Today, consumers are more conscious about nutrition and food products with health benefits. In this study, partial sucrose replacement (20%) with steviol glycosides derived from Stevia Rebaudiana and total replacement of cocoa powder with cocoa fibre preparation in muffins were conducted. There were three levels of dietary fibre addition – 3%, 6% and 12%. Physical analysis of texture, colour, cooking yield and porosity was conducted. Moreover, chemical analysis of total dietary fibre and total phenol content was made as well. Sensory evaluation in two parts was also carried out. The experiment revealed the increase in firmness, porosity, TDF and TCP and the decrease in springiness, cohesiveness and lightness. The best‐ranked sample in sensory evaluation was muffin with 6% of TDF sweetened with mixture of sugar and stevia. Stevia addition enhanced cocoa and sweet taste in tested muffins.     

Multi-criteria decision algorithms for efficient content delivery in content networks

Today’s Internet is prominently used for content distribution. Various platforms such as content delivery networks (CDNs) have become an integral part of the digital content ecosystem. Most recently, the information-centric networking (ICN) paradigm proposes the adoption of native content naming for secure and efficient content delivery. This further enhances the flexibility of content access where a content request can be served by any source within the Internet. In this paper, we propose and evaluate a multi-criteria decision algorithm for efficient content delivery applicable for content networks in general (among others, CDN and ICN). Our algorithm computes the best available source and path for serving content requests taking into account information about content transfer requirements, location of the consumer, location of available content servers, content server load and content delivery paths between content servers and consumer. The proposed algorithm exploits two closely related processes. The first level discovers multiple content delivery paths and gathers their respective transfer characteristics. This discovery process is based on long-term network measurements and performed offline. The second process is invoked for each content request to find the best combined content server and delivery path. The cooperation between both levels allows our algorithm to increase the number of satisfied content requests thanks to efficient utilisation of network and server resources. The proposed decision algorithm was evaluated by simulation using Internet scale network model. The results confirm the effectiveness gain of content network architectures that introduce network awareness. Moreover, the simulation process allows for a comparison between different routing algorithms and, especially, between single and multipath routing algorithms.     

Fill-ins number reducing direct solver designed for FIT-type matrix

This paper investigates the particular problem of matrices appearing during the modeling of Integrated Circuits with Finite Integration Technique (FIT) method. We present the key points of FIT approach followed by an illustration of the structure and the properties of the FIT-type matrix. A novel algorithm SMark is proposed, which focuses on fill-ins number reduction. The main idea of SMark is the concept of a dual architecture—symbolic and numeric factorization.